3-Benzyl-7-meth­oxy-9-phenyl-2-tosyl-2,3,3a,4,9,9a-hexa­hydro-1H-pyrrolo[3,4-b]quinoline

نویسندگان

  • K. Chinnakali
  • D. Sudha
  • M. Jayagobi
  • R. Raghunathan
  • Hoong-Kun Fun
چکیده

In the title compound, C(32)H(32)N(2)O(3)S, the pyrrolidine ring adopts an envelope conformation with the methine C atom nearest to the phenyl ring as the flap atom. The tetra-hydro-pyridine ring has a half-chair conformation. The two rings are trans-fused. The phenyl ring bound to the tetra-hydro-pyridine is oriented almost perpendicular [dihedral angle = 86.35 (10)°] to the fused benzene ring. The dihedral angle between the benzyl-phenyl ring and the sulfonyl-bound phenyl ring is 69.43 (10)°. A very weak N-H⋯π inter-action is observed in the mol-ecular structure. In the crystal, mol-ecules translated one unit along the b axis are linked into C(10) chains by C-H⋯O hydrogen bonds; adjacent chains are linked via C-H⋯π inter-actions, forming a two-dimensional network parallel to the bc plane.

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3-Benzyl-9-phenyl-2-tosyl-2,3,3a,4,9,9a-hexa­hydro-1H-pyrrolo[3,4-b]quinoline

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عنوان ژورنال:

دوره 65  شماره 

صفحات  -

تاریخ انتشار 2009